Solid state NMR on catalytic materials

Supported metal nanoparticles (NP) are an important class of catalysts. Many techniques can contribute to shed light on their structure, for instance, XAS is well placed to look at the metallic active sites, IR is powerful to look at absorbed functional groups, but solid state NMR has been under-explored on…

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Flame Synthesis of Catalysts and Applications

Flame aerosol synthesis (FAS) is an established method of synthesizing nanoparticles. It remains to account for the production of the majority of commercial nanoparticulate products including but not limited to carbon black, fumed silica, and the benchmark photocatalyst, P25 TiO2.  FAS is a continuous flow process where precursor vapors or micro-droplets…

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Sonochemical CO2 reduction over copper-based catalysts

There exists a critical need to develop sustainable and green technologies to convert the atmospheric CO2 into high-value chemicals and feedstocks, in turn helping to expedite the progress toward a Net Zero society.1 To this end, CO2 reduction (CO2R) technologies has been highlighted as one of the research forefronts,2 with various methodologies implemented aiming…

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Using In Situ Vibrational Spectroscopy to Probe (Electro)Catalytic Interfaces

The combination of electrochemical methods with molecular spectroscopy can provide valuable information about chemical processes at electrode-electrolyte interfaces. In particular, Raman and infrared spectroscopies have been shown to yield unique mechanistic insights into chemical reactions at electrodes by enabling fingerprinting of surface species via identification of characteristic vibrational modes. These powerful tools…

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Computational Modelling as a Tool in Catalytic Science

A special collection of thematically related manuscripts by UK Catalysis Hub members has been published by the Royal Society in 2023 PCCP Reviews, Phys. Chem. Chem. Phys., 2023, Advance Article. Computational modelling techniques now play a vital role in catalytic science. Atomic and molecular level simulation is used widely and…

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